Chemistry notes · Chapter 11 of 11

Radioactivity & Nuclear Chemistry

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What Is Radioactivity?

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What is radioactivity?

The spontaneous emission of invisible rays by certain unstable elements. It happens on its own, without any external push like heat, light or chemicals.

Is radioactivity a chemical or nuclear property?

Nuclear — the radiation comes from the nucleus, not the electrons. It cannot be started or stopped by heating, cooling, pressure or chemical reactions.

When does a nucleus become radioactive, and which elements are common?

When it holds too many protons and neutrons to stay balanced. Common ones: uranium, radium, thorium and polonium.

History & Discovery

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Who discovered radioactivity, and when?
Henri Becquerel in 1896, from uranium salts. He also coined the term 'radioactivity'.

Henri Becquerel in 1896, from uranium salts. He also coined the term 'radioactivity'.

Who shared the 1903 Nobel Prize in Physics?

The Curies and Becquerel.

What did Rutherford and Soddy contribute?

Rutherford identified alpha and beta rays and proved alpha is a helium nucleus. Frederick Soddy explained how one element changes into another and introduced isotopes.

What are the units of radioactivity?

The Becquerel (1 decay per second) and the Curie.

Henri BecquerelWho is this, and what should you remember about them?

Henri Becquerel

  • Henri Becquerel discovered radioactivity in 1896 from uranium salts.

The Three Rays – Alpha, Beta, Gamma

RayChargeStopped by
Alpha (α)+2 (He nucleus)Paper / skin
Beta (β)−1 (electron)Thin aluminium
Gamma (γ)0 (wave)Thick lead / concrete
Alpha, beta, gamma rays – penetration through paper, aluminium, lead
Alpha, beta, gamma rays – penetration through paper, aluminium, lead

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What is an alpha particle?

A helium nucleus — 2 protons + 2 neutrons, charge +2, mass 4. Gaining 2 electrons it becomes ordinary helium gas.

What is a beta ray?

A stream of fast-moving electrons thrown out of the nucleus, charge −1, negligible mass.

What is a gamma ray?

Pure energy — an electromagnetic wave like X-rays, with no charge and no mass, travelling at the speed of light.

How do the three rays behave in an electric field?
Alpha bends to the negative plate, beta to the positive plate, gamma goes straight.

Alpha bends to the negative plate, beta to the positive plate, gamma goes straight.

Give the penetrating power order.
Gamma > beta > alpha (gamma ≈1000×, beta ≈100× alpha).

Gamma > beta > alpha (gamma ≈1000×, beta ≈100× alpha).

Give the ionising power order.
Alpha > beta > gamma — the exact reverse of penetration.

Alpha > beta > gamma — the exact reverse of penetration.

What stops each ray?
Alpha — paper or skin · Beta — thin aluminium · Gamma — thick lead or concrete.

Alpha — paper or skin · Beta — thin aluminium · Gamma — thick lead or concrete.

Ray: Alpha (α) → Charge · Stopped by?
Charge
+2 (He nucleus)
Stopped by
Paper / skin
Ray: Beta (β) → Charge · Stopped by?
Charge
−1 (electron)
Stopped by
Thin aluminium
Ray: Gamma (γ) → Charge · Stopped by?
Charge
0 (wave)
Stopped by
Thick lead / concrete
What does this diagram show?

Alpha, beta, gamma rays – penetration through paper, aluminium, lead

Properties of the Three Rays (Compare)

PropertyAlphaBetaGamma
NatureHe nucleusElectronEM wave
Charge+2−10
Mass (u)4≈00
PenetrationLeastMediumMost
IonisationMostMediumLeast

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is highest for alpha and zero for gamma.

Mass is highest for alpha and zero for gamma.

rises from alpha to gamma; gamma travels at the speed of light.

Speed rises from alpha to gamma; gamma travels at the speed of light.

Note the two reversed orders: vs ionisation (α>β>γ).

Note the two reversed orders: penetration (γ>β>α) vs ionisation (α>β>γ).

Property: Nature → Alpha · Beta · Gamma?
Alpha
He nucleus
Beta
Electron
Gamma
EM wave
Property: Charge → Alpha · Beta · Gamma?
Alpha
+2
Beta
−1
Gamma
0
Property: Mass (u) → Alpha · Beta · Gamma?
Alpha
4
Beta
≈0
Gamma
0
Property: Penetration → Alpha · Beta · Gamma?
Alpha
Least
Beta
Medium
Gamma
Most
Property: Ionisation → Alpha · Beta · Gamma?
Alpha
Most
Beta
Medium
Gamma
Least

Atomic Number & Mass Number

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is the number of protons; it decides which element the atom is.

Atomic number (Z) is the number of protons; it decides which element the atom is.

is the total of protons plus neutrons.

Mass number (A) is the total of protons plus neutrons.

A nucleus is written as , e.g. ¹⁴C means A=14.

A nucleus is written as ᴬZ-symbol, e.g. ¹⁴C means A=14.

Electrons have almost no mass, so they are in mass number.

Electrons have almost no mass, so they are not counted in mass number.

Isotopes vs Isobars

FeatureIsotopesIsobars
Atomic no. (Z)SameDifferent
Mass no. (A)DifferentSame
ElementSameDifferent
Example¹²C, ¹⁴C¹⁴C, ¹⁴N
Isotopes vs Isobars
Isotopes vs Isobars

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: same element, same atomic number (Z), but different mass number (A).

Isotopes: same element, same atomic number (Z), but different mass number (A).

Isotopes have the same protons but a number of neutrons.

Isotopes have the same protons but a different number of neutrons.

Hydrogen isotopes: tritium (³H).

Hydrogen isotopes: protium (¹H), deuterium (²H), tritium (³H).

Abundance: , 0.015% deuterium, traces of radioactive tritium.

Abundance: 99.985% protium, 0.015% deuterium, traces of radioactive tritium.

: same mass number (A) but different atomic number – so different elements.

Isobars: same mass number (A) but different atomic number – so different elements.

Classic isobar pair: .

Classic isobar pair: ¹⁴C (Z=6) and ¹⁴N (Z=7).

Feature: Atomic no. (Z) → Isotopes · Isobars?
Isotopes
Same
Isobars
Different
Feature: Mass no. (A) → Isotopes · Isobars?
Isotopes
Different
Isobars
Same
Feature: Element → Isotopes · Isobars?
Isotopes
Same
Isobars
Different
Feature: Example → Isotopes · Isobars?
Isotopes
¹²C, ¹⁴C
Isobars
¹⁴C, ¹⁴N
What does this diagram show?

Isotopes vs Isobars

Half-Life & Rate of Decay

Half-lives passedSample left
0100%
150%
225%
312.5%
46.25%
Half-Life & Rate of Decay
Half-Life & Rate of Decay

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What is half-life?
The time for exactly half of a radioactive sample to decay. It is fixed for each element and unaffected by temperature, pressure or chemical state.

The time for exactly half of a radioactive sample to decay. It is fixed for each element and unaffected by temperature, pressure or chemical state.

How much is left after n half-lives?

(1/2)ⁿ of the original — 100% → 50% → 25% → 12.5% → 6.25%. It never reaches zero.

Half-lives of carbon-14, uranium-238 and radium-226?

C-14 ≈ 5770 years (radiocarbon dating) · U-238 ≈ 4.5 billion years · Ra-226 ≈ 1600 years. Huge half-lives explain why such elements still exist on Earth.

After each half-life the remaining amount halves: 25% → 12.5%.

After each half-life the remaining amount halves: 50% → 25% → 12.5%.

Half-lives passed: 0 → Sample left?
Sample left
100%
Half-lives passed: 1 → Sample left?
Sample left
50%
Half-lives passed: 2 → Sample left?
Sample left
25%
Half-lives passed: 3 → Sample left?
Sample left
12.5%
Half-lives passed: 4 → Sample left?
Sample left
6.25%
What does this diagram show?

Half-Life & Rate of Decay

Mass-Energy & Nuclear Fission

Mass-Energy & Nuclear Fission
Mass-Energy & Nuclear Fission

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What is nuclear fission?
A heavy nucleus (e.g. uranium-235) splits into two smaller nuclei, releasing great energy plus extra neutrons that split more nuclei — a chain reaction. Picture a big rock breaking into pieces.

A heavy nucleus (e.g. uranium-235) splits into two smaller nuclei, releasing great energy plus extra neutrons that split more nuclei — a chain reaction. Picture a big rock breaking into pieces.

Atomic bomb vs nuclear reactor?

An uncontrolled chain reaction powers the atomic bomb; a controlled one runs a nuclear reactor.

What does E = mc² mean here?
Einstein's relation — a tiny loss of mass releases enormous energy. This mass-to-energy conversion is the source of all nuclear energy.

Einstein's relation — a tiny loss of mass releases enormous energy. This mass-to-energy conversion is the source of all nuclear energy.

Those freed neutrons can split more nuclei, causing a self-sustaining .

Those freed neutrons can split more nuclei, causing a self-sustaining chain reaction.

What does this diagram show?

Mass-Energy & Nuclear Fission

Nuclear Fusion

FeatureFissionFusion
ProcessHeavy nucleus splitsLight nuclei combine
ExampleUranium-235Hydrogen → Helium
WeaponAtomic bombHydrogen bomb
Occurs inReactorSun & stars
Nuclear fission vs fusion
Nuclear fission vs fusion

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What is nuclear fusion?
Two light nuclei join to form a heavier nucleus, releasing energy. It needs extremely high temperature and pressure and powers the Sun and stars (hydrogen into helium).

Two light nuclei join to form a heavier nucleus, releasing energy. It needs extremely high temperature and pressure and powers the Sun and stars (hydrogen into helium).

Which principle powers the hydrogen bomb?
Nuclear fusion, NOT fission. Fission powers the atom bomb. Fusion releases far more energy per unit mass.

Nuclear fusion, NOT fission. Fission powers the atom bomb. Fusion releases far more energy per unit mass.

Picture fusion as – the opposite of fission.

Picture fusion as small pieces joining into a bigger one – the opposite of fission.

Feature: Process → Fission · Fusion?
Fission
Heavy nucleus splits
Fusion
Light nuclei combine
Feature: Example → Fission · Fusion?
Fission
Uranium-235
Fusion
Hydrogen → Helium
Feature: Weapon → Fission · Fusion?
Fission
Atomic bomb
Fusion
Hydrogen bomb
Feature: Occurs in → Fission · Fusion?
Fission
Reactor
Fusion
Sun & stars
What does this diagram show?

Nuclear fission vs fusion

Atomic Bombs of 1945

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What fissionable material was used at Hiroshima and at Nagasaki?

Hiroshima — uranium-235; Nagasaki — plutonium-239 ('Fat Man'). Both worked on an uncontrolled fission chain reaction.

Two atomic (fission) bombs were dropped on Japan in .

Two atomic (fission) bombs were dropped on Japan in 1945.

Uses & Hazards of Radioactivity

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Give the main uses of radioactivity.

Radiocarbon (C-14) dating of fossils and wood · nuclear reactors for electricity · cobalt-60 and gamma rays for cancer · tracers in diagnosis · iodine-131 for thyroid disorders.

What are the hazards, and what shielding is needed?

Radiation damages living cells and can cause cancer and genetic harm. Protection requires thick lead or concrete.

finds the age of fossils, wood and old objects.

Radiocarbon (C-14) dating finds the age of fossils, wood and old objects.

use controlled fission to generate electricity.

Nuclear reactors use controlled fission to generate electricity.

Radioactive are used in medical diagnosis and to study processes.

Radioactive tracers are used in medical diagnosis and to study processes.

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