Chemistry PYQ 121 of 291 · Organic Chemistry

Alcohol can be converted to carboxylic acid

  1. ABy oxidation only
  2. BBy reduction only
  3. CBy esterification
  4. DBy both oxidation and reduction
  5. ENone of the above/More than one of the above

65th BPSC Prelims Re-exam 2020

Show answer and explanation

Correct answer: (a) By oxidation only

Explanation

A primary alcohol becomes a carboxylic acid by oxidation, for example with acidified potassium dichromate or permanganate:

R–CH₂OH → R–CHO (aldehyde) → R–COOH (carboxylic acid)

So ethanol oxidises to acetic acid; this is also how wine turns into vinegar. Esterification is the reverse kind of reaction: an acid and an alcohol joining to form an ester.

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