Chemistry PYQ 63 of 346 · Chemical Bonding

Water and ammonia molecules:

  1. AWater has sp² and NH₃ has sp³ hybridisation, and their bond angles are 109° and 107° respectively
  2. BBoth have sp³ hybridisation and the same bond angle of 104.5°
  3. CBoth have sp³ hybridisation, and their bond angles are 104.5° and 107° respectively
  4. DWater has sp³ and NH₃ has sp² hybridisation, and their bond angles are 104.5° and 109° respectively

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Correct answer: (c) Both have sp³ hybridisation, and their bond angles are 104.5° and 107° respectively

Explanation

In both molecules, the central atom has four electron pairs, so both are sp³ hybridised:

  • water (H₂O): two bonds and two lone pairs; the lone pairs push the bonds closer, giving a bond angle of about 104.5° (a bent shape);
  • ammonia (NH₃): three bonds and one lone pair; the bond angle is about 107° (a pyramidal shape).

Without lone pairs, as in methane, the angle is 109.5°. Lone pairs repel more than bonding pairs, and two lone pairs squeeze the angle more than one.

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