Chemistry PYQ 23 of 152 · Chemical Bonding

What is the shape of sulphur hexafluoride molecule?

  1. ATrigonal pyramid
  2. BOctahedral
  3. CPlanar
  4. DTetrahedral

45th BPSC

Show answer and explanation

Correct answer: (b) Octahedral

Explanation

In SF6 the central sulphur atom is surrounded by 6 bond pairs (12 shared electrons) and has no lone pairs.

Six identical bonding regions arrange themselves symmetrically, giving an octahedral geometry (90 degree bond angles).

Absence of lone pairs rules out trigonal pyramidal, planar or tetrahedral shapes.

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